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Membraneless and Electrochemical Carbon Capture: Disrupting Traditional Amine-Based Systems for Industrial De-carbonization: A Review

膜不要・電気化学的炭素回収:従来のアミン系システムを打破する産業脱炭素化技術のレビュー (AI 翻訳)

Enang . A et al 2026 Idongest., Jamilu, Musa. G, Akinlotan, Omoyeni. O, Jibril, Abdulrahman. S, Adegboyo, Opeyemi, Olabimtan, Olabode.H

Zenodo (CERN European Organization for Nuclear Research)📚 査読済 / ジャーナル2026-05-04#CCUSOrigin: Global
DOI: 10.5281/zenodo.20026956
原典: https://doi.org/10.5281/zenodo.20026956

🤖 gxceed AI 要約

日本語

本レビューは、膜不要電気化学的炭素回収技術を従来のアミン吸収法と比較し、CO₂除去効率90%以上、エネルギー消費60 kJ mol⁻¹ CO₂、コスト70 USD t⁻¹を達成する可能性を示す。pHスイング法や反応スイング法などの補完技術も評価し、産業規模での実現には電流密度向上と長期安定性が課題である。

English

This review critically assesses membraneless and electrochemical carbon capture (e.g., EMAR, pH-swing) against conventional amine scrubbing, highlighting >90% CO₂ removal efficiency, ~60 kJ mol⁻¹ energy consumption, and ~70 USD/t cost. It also evaluates integrated reaction-swing schemes for direct syngas production. Key challenges remain in achieving industrial current densities and sorbent durability.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本ではCCUSがカーボンニュートラル達成に向けた重要技術と位置づけられており、本レビューは従来のアミン法に代わる電気化学的アプローチの可能性を包括的に示す。電力駆動で柔軟な運用が可能な点は、再生可能エネルギー導入が進む日本にとって特に有望である。

In the global GX context

This review provides a timely comparison of emerging electrochemical carbon capture technologies with incumbent amine scrubbing, relevant for global industrial decarbonization. The low energy penalty and modularity align with electrification trends and integration with renewable energy, offering a pathway for hard-to-abate sectors.

👥 読者別の含意

🔬研究者:Provides a comprehensive overview of recent advances in membraneless and electrochemical carbon capture, useful for identifying research gaps and promising directions.

🏢実務担当者:Offers performance benchmarks (energy consumption, cost) that can inform technology selection for industrial carbon capture projects.

🏛政策担当者:Highlights the potential of electrically driven CCS as a flexible decarbonization option, supporting policy frameworks that incentivize innovation in carbon removal technologies.

📄 Abstract(原文)

Electrochemical carbon capture is emerging as a promising alternative to thermally driven amine scrubbing fordecarbonising challenging industrial sectors. This review critically assesses recent advances in membraneless andother electrochemical approaches in comparison to conventional amine-based post-combustion capture.Membraneless electrochemically mediated amine regeneration (EMAR) architectures replace ion-selectivemembranes with gas-diffusion electrodes, collapsing absorption and desorption into a single electrochemical unitand eliminating ancillary equipment, such as columns and flash tanks. This redesign delivers CO₂ removalefficiencies above 90% at energy consumptions as low as ~60 kJ mol⁻¹ CO₂ and levelized capture costs near 70 USDt⁻¹, substantially below conventional EMAR and competitive with state-of-the-art thermal systems. Complementaryconcepts, including electrochemical pH-swing regeneration of amine solutions, exploit amines as buffers tomaintain favorable inorganic carbon speciation and achieve high current utilization with minimum energies near 60kJ mol⁻¹ CO₂ while preserving product purity. Integrated “reaction-swing” schemes directly electroreduce CO₂captured in tailored amine solvents to syngas, demonstrating high absorption (>84%) and improved Faradaicefficiencies, thereby circumventing separate solvent regeneration and gas compression steps. These developmentsare contextualised against the chemistry, performance and deployment of incumbent amine scrubbing and emerging electroswing systems for industrial decarbonization. The outstanding issues are to reach industrially relevant current densities and lifetimes, sorbent stability, and to incorporate electrochemical units into large-scale process flows. Convincingly, membraneless and electrochemical carbon capture technologies have a promising future in potentially replacing traditional amine systems through lower energy penalties, reducing process layouts, and allowing a flexible and electricity driven net-zero industrial process

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