Coupled Raman and FTIR Analysis of Biomass-Derived Carbon Prepared at Low Carbonization Temperature
低炭化温度で調製したバイオマス由来カーボンのラマン・FTIR連携解析 (AI 翻訳)
Gugus Handika, Fairuz Gianirfan Nugroho, Afina Faza Hafiyyan, Feber Valentin Br Sembiring, Neysa Azzahra, Abu Saad Ansari, Nurul Taufiqu Rochman
🤖 gxceed AI 要約
日本語
本研究は、オイルパーム空果房から500℃の熱分解で調製したバイオマスカーボンを、FTIRとラマン分光法を用いて解析した。低炭化温度では、小さな無秩序なsp2炭素ドメインが形成され、欠陥リッチな芳香族炭素構造が生じることを示した。この構造は吸着や触媒に有用であり、廃棄物の価値化に貢献する。
English
This study characterizes biomass-derived carbon from oil palm empty fruit bunches pyrolyzed at 500°C using coupled FTIR and Raman spectroscopy. Low-temperature pyrolysis yields a defect-rich aromatic carbon structure with small disordered sp2 domains, suitable for adsorption, catalysis, and environmental remediation, highlighting a valorization pathway for agricultural waste.
Unofficial AI-generated summary based on the public title and abstract. Not an official translation.
📝 gxceed 編集解説 — Why this matters
日本のGX文脈において
日本ではパーム油輸入に伴う廃棄物処理が課題となっており、本成果はバイオマス廃棄物の有効活用や低炭素材料開発の観点から参考になる。ただし、直接的な政策連動は限定的。
In the global GX context
Globally, the study offers insights into producing functional carbon materials from agricultural waste at low energy cost, supporting circular economy and carbon sequestration efforts. It provides a basis for developing biochar and activated carbon from residues, relevant to waste management and carbon removal technologies.
👥 読者別の含意
🔬研究者:Provides detailed spectroscopic evidence for carbon structure at low pyrolysis temperatures, useful for designing biomass-derived functional materials.
🏢実務担当者:Offers a method to tailor carbon properties from specific feedstock, potentially applicable to waste valorization and biochar production.
📄 Abstract(原文)
Biomass-derived carbon is commonly produced at high temperatures to promote graphitization; however, understanding carbon formation at lower temperatures remains critical for applications that rely on surface reactivity rather than crystallinity. In this work, carbon obtained from oil palm empty fruit bunch (EFB) through pyrolysis at 500 °C was systematically investigated using coupled Fourier transform infrared (FTIR) and Raman spectroscopy, supported by density functional theory (DFT)-based structural interpretation. FTIR analysis reveals extensive dehydration, cleavage of aliphatic C–H bonds, and progressive loss of oxygenated functional groups, accompanied by the emergence of aromatic C=C and C–O–C linkages. Raman spectra, resolved through pseudo-Voigt deconvolution, are dominated by defect-related bands (D, D2, D3, and D4) with a broadened G band, indicating the formation of small, disordered sp2 carbon domains rather than extended graphitic lattices. DFT-assisted analysis suggests that the carbon framework is composed of interconnected polyaromatic hydrocarbon clusters incorporating residual heteroatoms and mixed sp2–sp3bonding. These results demonstrate that low-temperature pyrolysis of EFB produces a defect-rich aromatic carbon structure strongly governed by precursor chemistry, offering a viable route for tailoring functional carbon materials with abundant active sites, making it highly suitable for applications in adsorption, catalysis, and environmental remediation technologies.
🔗 Provenance — このレコードを発見したソース
- openalex https://doi.org/10.21009/jrskt.121.04first seen 2026-06-26 05:01:29
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