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Nanomaterial-Based Photocatalysts for Sustainable Bioenergy Production

ナノ材料ベースの光触媒による持続可能なバイオエネルギー生産 (AI 翻訳)

Kankana Saikia, Soumitra Nath, Suprakash Rabha, Kanokwan Ngaosuwan, Umer Rashid, Samuel Lalthazuala Rokhum

ジャーナル2026-04-23#再生可能エネルギー
DOI: 10.1201/9781003650683-7
原典: https://doi.org/10.1201/9781003650683-7

🤖 gxceed AI 要約

日本語

本論文は、ナノ材料光触媒を用いた持続可能なバイオエネルギー生産について包括的にレビューする。TiO2、ZnO、CdS、g-C3N4、ペロブスカイト、MOF、ハイブリッド複合材料などが紹介され、光触媒前処理によりリグニン分解が促進され、糖放出が最大260%向上、水素収率47%増、メタン収率158%増が報告されている。また、CO2光還元によるギ酸生成速度430 μmol g⁻¹ h⁻¹、水素生成速度14.67 mmol g⁻¹ h⁻¹などの成果が示され、課題として触媒安定性、回収、コスト、スケールアップが挙げられる。

English

This chapter reviews nanomaterial-based photocatalysts for sustainable bioenergy production, covering TiO2, ZnO, CdS, g-C3N4, perovskites, MOFs, and hybrids. Photocatalytic pretreatment enhances lignin breakdown, boosting sugar release by up to 260%, hydrogen yields by 47%, and methane yields by 158%. CO2 photoreduction achieves formic acid production >430 μmol g⁻¹ h⁻¹, and hydrogen production reaches 14.67 mmol g⁻¹ h⁻¹. Challenges include catalyst stability, recovery, cost, and scale-up.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本は水素社会の実現やバイオマス活用を推進しており、本レビューは光触媒による水素・メタン生成の向上事例を提供する。ただし、実用化には触媒の耐久性や大規模合成の課題があり、日本の産業応用にはさらなる研究開発が必要。

In the global GX context

This review aligns with global energy transition efforts by highlighting photocatalytic routes for bioenergy and hydrogen. It supports carbon neutrality goals through solar-driven biomass conversion and CO2 reduction, but remains at the fundamental research stage.

👥 読者別の含意

🔬研究者:Provides a comprehensive overview of photocatalyst materials and their bioenergy applications, useful for identifying research directions.

📄 Abstract(原文)

Nanomaterial-based photocatalysts represent a cutting-edge approach for advancing sustainable bioenergy generation, facilitating solar-driven biomass conversion, hydrogen production, CO2 reduction, and bio-oil upgrading under mild and environmentally friendly conditions. This chapter presents an extensive overview of prominent nanomaterials including TiO2, ZnO, CdS, g-C3N4, perovskites, MOFs, and hybrid composites, emphasizing their high surface areas, tunable bandgaps, and strong redox properties. Evidence from recent research shows that photocatalytic pretreatment can significantly accelerate lignin breakdown, lower crystallinity, and boost sugar release by as much as 260%, thereby achieving notable increases in hydrogen yields (up to 47%) and methane yields (up to 158%). In combined hydrolysis–fermentation processes, nano-photocatalysts reduce microbial lag phases and enhance hydrogen output by more than 100% by promoting superior charge transfer and increasing enzymatic activity. For CO2 photoreduction, engineered heterojunctions enable the targeted synthesis of value-added compounds such as formic acid at rates exceeding 430 μmol g⁻1 h⁻1, while biomass-derived catalysts for hydrogen generation achieve production rates of up to 14.67 mmol g⁻1 h⁻1 under solar irradiation. In the context of bio-oil upgrading, atomically dispersed single-atom catalysts attain greater than 98% selectivity for key monomers, and nanostructured zeolites along with metal–organic hybrids boost aromatic yields and deoxygenation efficiencies to over 90%. Despite these advances, challenges remain in catalyst stability, recovery, cost-effective synthesis, and scale-up. Addressing these through interdisciplinary innovations in materials science, reactor engineering, and environmental safety will be essential for realizing large-scale, light-assisted biorefineries that align with global carbon neutrality goals.

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