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Effect of Water–Solid Ratio on the Performance, Microstructure Evolution, and Low-Carbon Characteristics of Multi-Solid-Waste-Based Flowable Stabilized Soil

水固比が複合固形廃棄物ベースの流動性安定化土の性能、微細構造進化、および低炭素特性に及ぼす影響 (AI 翻訳)

Jiaojiao Ni, Qing Jiang, Qiwei Zhan, Haitao Hu, Yongqi Zhao

Materials📚 査読済 / ジャーナル2026-05-26#エネルギー転換Origin: CN
DOI: 10.3390/ma19112247
原典: https://doi.org/10.3390/ma19112247

🤖 gxceed AI 要約

日本語

本研究は、ソーダ残渣、高炉スラグ、リン石膏等の産業廃棄物を80%配合したジオポリマー系固化材(SGPC)を開発し、水固比が安定化土の性能に与える影響を調査。最適水固比0.43にて、28日強度1.45MPaを達成し、CO2排出量を74.7%削減(235 kg-CO2/t)、コストを51.8%低減。微細構造解析により、エトリンガイトとC-(A)-S-Hゲルの緻密化が強度向上に寄与することを確認。

English

This study develops a geopolymer cement (SGPC) using 80% industrial solid wastes (soda residue, slag, phosphogypsum). At optimal water-solid ratio 0.43, it achieves 28-day compressive strength of 1.45 MPa, reduces CO2 emissions by 74.7% (235 kg-CO2/t), and cuts material cost by 51.8%. Microstructural analysis reveals that ettringite and C-(A)-S-H gel formation densifies the matrix, enhancing strength.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本では建設発生土の処理や産業廃棄物の有効活用が課題であり、本技術はセメント代替としてCO2削減と廃棄物削減の両立が期待される。ただし、使用する廃棄物の種類や組成が異なる場合の適用性には注意が必要。

In the global GX context

This work demonstrates a scalable, low-carbon alternative to conventional cement stabilizers, achieving significant CO2 and cost reductions. It aligns with global efforts to decarbonize construction materials and valorize industrial waste, contributing to circular economy goals.

👥 読者別の含意

🔬研究者:Quantitative data on strength, microstructure, and LCA provide a benchmark for further optimization of waste-based geopolymers.

🏢実務担当者:Offers a ready-to-use formulation with verified performance and environmental benefits for soil stabilization in construction.

🏛政策担当者:Supports policies promoting industrial waste utilization and low-carbon building materials with clear emission reduction metrics.

📄 Abstract(原文)

To promote the high-value utilization of industrial solid wastes and address the disposal of excavated soils, a novel low-carbon composite cementitious material, solid waste-based geopolymer cement (SGPC), was developed, consisting of soda residue (SR), granulated blast furnace slag (GGBS), phosphogypsum (PG), and ordinary Portland cement (PC) in a mass ratio of 10:81:9:25, with industrial solid wastes accounting for 80% of the binder. The effects of water-to-solid ratio (W/S = 0.41–0.49) on the workability, mechanical performance, and microstructural evolution of SGPC-stabilized soil were systematically investigated to provide a sustainable alternative to conventional cement-based stabilizers. The results indicate that the optimum water-to-solid ratio is 0.43 (SGPC43), with a 28-day unconfined compressive strength of 1450 kPa, exceeding the engineering requirement of 0.8 MPa and reaching over 85% of that of a pure cement system (C43). The flowability remained 163 mm after 60 min, with initial and final setting times of 43 h and 58 h, respectively. Microstructural analysis revealed that the alkalinity provided by soda residue promotes the hydration of slag and phosphogypsum, forming interwoven calcium (alumino) silicate hydrate (C–(A)–S–H) and ettringite (AFt), which fill pores and form a dense structure, thereby enhancing mechanical performance. Environmental and economic assessments show that the CO2 emission of SGPC43 per ton of binder decreases from 930 kg CO2-e/t to 235 kg CO2-e/t (approximately 74.7% reduction), while the material cost decreases from 110 USD/t to 53 USD/t (approximately 51.8% reduction). A simplified uncertainty analysis indicates that the carbon reduction remains at 70% ± 5% and the cost reduction at 50% ± 5%, confirming the robustness of the results. Overall, SGPC43 demonstrates excellent engineering performance, environmental benefits, and economic feasibility, highlighting its potential as a low-carbon and sustainable stabilizing material.

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