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水分解用遷移金属系オキシ水酸化物電極触媒におけるドーピングとヘテロ構造戦略:レビュー

Doping and heterostructure strategies in transition metal-based oxyhydroxide electrocatalysts for water splitting: review (原題)

Haripal Singh Dhayal, Jyotiprakash B. Yadav, Rupesh S. Devan, Nishad G. Deshpande

Journal of Physics D Applied Physics📚 査読済 / ジャーナル2026-08-04#水素対象セクター: energy
DOI: 10.1088/1361-6463/ae948a
原典: https://doi.org/10.1088/1361-6463/ae948a

🤖 gxceed AI 要約

日本語

本レビューは、グリーン水素製造のための水分解反応における遷移金属オキシ水酸化物(TMOxHy)電極触媒の重要性を包括的に解説する。元素ドーピング、ヘテロ構造工学、ナノ構造化などの戦略が触媒活性と耐久性に与える影響を系統的に評価し、電解質系による挙動の違いも分析する。電荷移動の制限や長期安定性などの課題を指摘し、持続可能なエネルギー変換技術への展望を示す。

English

This review comprehensively examines transition metal oxyhydroxide (TMOxHy) electrocatalysts for water splitting, a key process for green hydrogen production. It systematically evaluates enhancement strategies such as elemental doping, heterostructure engineering, and nanostructuring, and analyzes their effects on catalytic activity and durability across various electrolytes. Key challenges like charge transfer limitations and long-term stability are discussed, with future perspectives for sustainable energy conversion.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本の水素戦略(水素基本戦略、グリーンイノベーション基金)に直結する技術であり、国産の高効率電極触媒開発は水素コスト低減に寄与する。基礎研究段階だが、産業界との連携による実用化が期待される。

In the global GX context

This review contributes to global efforts in green hydrogen production, a cornerstone of the energy transition. It provides a comprehensive overview of TMOxHy electrocatalysts, offering insights for researchers and industry aiming to improve efficiency and reduce costs of water electrolysis, aligning with global hydrogen strategies and decarbonization targets.

👥 読者別の含意

🔬研究者:Provides a systematic overview of TMOxHy electrocatalyst design strategies, useful for guiding future research directions in water splitting.

🏢実務担当者:Offers insights into catalyst development that could inform investments in green hydrogen production technologies, though practical application is still distant.

🏛政策担当者:Highlights the potential of TMOxHy-based catalysts for advancing green hydrogen, supporting policy decisions on R&D funding and hydrogen infrastructure.

📄 Abstract(原文)

Abstract Electrocatalytic processes for green energy production are of growing importance as they offer efficient energy conversion while maintaining environmental sustainability. In this context, transition metal oxyhydroxides (TMOxHy) have emerged as highly promising electrocatalyst candidates due to their intrinsic oxygen redox activity, structural robustness, and abundance of earth-derived elements. This review comprehensively examines the important characteristics and requisite strategies of TMOxHy materials, emphasizing their critical influence on catalytic performance. Various enhancement approaches-including surface and compositional modulation, elemental doping with transition metals, non-metals, and carbon-based species, cocatalyst integration, heterostructure engineering, and nanostructuring-are systematically evaluated for their roles in improving catalytic activity and durability. In addition, the electrocatalytic behavior of TMOxHy materials across diverse electrolyte systems is analyzed. Finally, key challenges such as charge transfer limitations, long-term operational stability, and electrode corrosion are discussed, and future perspectives for advancing TMOxHy -based electrocatalysts toward sustainable energy conversion technologies are proposed.

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