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Enhancing pyrolysis oil yield and quality via low-temperature catalytic pyrolysis of pet waste over activated carbon derived from euxideroxylon zwageri

低温度触媒熱分解によるペット廃棄物からの熱分解油収率と品質向上:Euxideroxylon zwageri由来活性炭を用いて (AI 翻訳)

Ahmad Yani, Widya Wijayanti, Mega Nur Sasongko, Slamet Wahyudi, Dwi Irawan

Mechanical Engineering for Society and Industry📚 査読済 / ジャーナル2026-07-22#エネルギー転換
DOI: 10.31603/mesi.16415
原典: https://doi.org/10.31603/mesi.16415

🤖 gxceed AI 要約

日本語

本研究では、Euxideroxylon zwageri由来の活性炭を触媒として用い、ポストコンシューマーPETを350℃までの低温で熱分解した。PET:EZAC=90:10で最大油収率80.8wt%を達成し、RON97、HHV47.88MJ/kgの高品質燃料を得た。GC-MS分析によりガソリン様組成が確認され、EZACが水素やメタンの生成を促進した。

English

This study evaluates low-temperature pyrolysis of post-consumer PET using activated carbon from Euxideroxylon zwageri (EZAC) as a renewable catalyst. At PET:EZAC=90:10, maximum oil yield of 80.8 wt% was achieved with fuel properties: RON 97, HHV 47.88 MJ/kg. GC-MS confirmed gasoline-like composition dominated by C7-C10 fraction (62.95%). EZAC accelerated H2 and CH4 formation. The catalyst improves both oil yield and quality.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本ではプラスチック資源循環が推進されており、低温度触媒熱分解によるPET廃棄物からの燃料油回収は、サーキュラーエコノミーと廃棄物発電の両面で参考となる。

In the global GX context

This paper contributes to global waste-to-energy and circular economy efforts by demonstrating a renewable catalyst for upgrading plastic pyrolysis oil. The low-temperature process offers energy efficiency and improved fuel quality, relevant for countries advancing chemical recycling and renewable fuel standards.

👥 読者別の含意

🔬研究者:Provides detailed catalytic performance data and optimal conditions for PET pyrolysis with biomass-derived activated carbon.

🏢実務担当者:Offers a promising technology for converting plastic waste into high-quality fuel, potentially applicable in waste management and recycling facilities.

📄 Abstract(原文)

This study evaluates the low-temperature pyrolysis of post-consumer polyethylene terephthalate (PET) from room temperature to 350 °C using biomass-derived activated carbon from Euxideroxylon zwageri (EZAC) as a renewable catalyst/adsorbent. PET–EZAC blends (100:0, 95:5, 90:10, 85:15, and 80:20; total feed 500 g) were processed in a fixed-bed reactor under an inert atmosphere. EZAC significantly shifted product distribution and exhibited an optimum at PET:EZAC = 90:10 (w/w), which produced the maximum oil yield of 543 mL (404 g; 80.8 wt%) and exceeded the oil yield from non-catalytic PET pyrolysis. Under this optimum condition, fuel-relevant properties improved, yielding an research octane number (RON) of 97 and a higher heating value (HHV) of 47.88 MJ/kg; the flash point and kinematic viscosity decreased to 13 °C and 2.384 cSt, respectively, while density remained nearly constant (0.772 g/mL). GC–MS results showed the most gasoline-like composition at PET:EZAC = 90:10, dominated by the C7–C10 fraction (62.95%) with a balanced hydrocarbon-class distribution (Alkanes 64.64%, Olefin 27.61%, and Aromatics 7.75%). MQ sensor-based gas profiles further suggested that EZAC accelerated the onset of H₂ and CH₄ formation, with peak sensor responses of 745 ppm for H₂ and 871 ppm for CH₄ at 20% EZAC. Overall, EZAC is a promising renewable material for steering secondary reactions during low-temperature PET pyrolysis, thereby improving both oil yield and oil quality.

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