Redefining the Nitrogen Cycle Through Electronic Configuration Driven Electrocatalysis for Low Carbon Energy
低炭素エネルギーのための電子配置駆動型電解触媒による窒素循環の再定義 (AI 翻訳)
Jiamu Feng, Linai Zhou, Mincan Yang, Aoxiang Zhu, Zengfeng Wei, Weilin Xu, J LI, Jun Wan
🤖 gxceed AI 要約
日本語
本稿は、窒素固定や反応性窒素種の排出による環境負荷を低減するため、電気化学的な窒素変換を統合的に捉える枠組みを提案する。電子配置に着目し、5つの主要な窒素変換反応を系統的に解析、dバンド特性やスピン状態など5つの電子制御次元を特定した。このアプローチにより、還元・酸化経路全体の機構理解を統一し、持続可能な低炭素窒素利用技術の設計原理を示す。
English
This review proposes an integrated framework for electrocatalytic nitrogen conversion, focusing on electronic configuration to unify understanding of five key nitrogen reactions. It identifies five dimensions of electronic regulation (d-band characteristics, oxidation/spin states, crystal field effects, defect-induced redistribution, heterostructure charge transfer) and positions them as system-level design principles for scalable low-carbon nitrogen utilization.
Unofficial AI-generated summary based on the public title and abstract. Not an official translation.
📝 gxceed 編集解説 — Why this matters
日本のGX文脈において
日本はアンモニアを水素キャリアや低炭素燃料として位置づけており、本稿の窒素循環電解触媒技術は、脱炭素エネルギーシステムへの応用可能性を示唆する。特に、再生可能エネルギー由来電力と組み合わせた窒素化合物の生成・分解は、日本のエネルギー安全保障にも寄与し得る。
In the global GX context
Globally, electrocatalytic nitrogen conversion offers a pathway to decarbonize fertilizer production and enable ammonia as a hydrogen carrier. This review's electronic-configuration-centered framework provides a mechanistic basis for designing efficient catalysts, relevant to efforts in renewable energy integration and circular nitrogen economy.
👥 読者別の含意
🔬研究者:Provides a unified mechanistic framework linking electronic configuration to electrocatalytic nitrogen conversion performance.
🏢実務担当者:May inform sustainable chemical process design for low-carbon ammonia and urea production.
📄 Abstract（原文）
ABSTRACT The global nitrogen cycle is essential to food production, chemical manufacturing, and emerging energy systems, yet it has been severely disrupted by fossil‐intensive nitrogen fixation and uncontrolled emissions of reactive nitrogen species. Electrocatalytic nitrogen conversion has emerged as a sustainable engineering paradigm that enables electrically driven interconversion of nitrogen species under mild conditions, offering a pathway toward circular nitrogen utilization coupled with renewable energy. Despite rapid progress, current research remains fragmented, largely treating nitrogen reduction, nitrate and nitrite reduction, and urea and ammonia oxidation as isolated processes. This review establishes an electronic‐configuration‐centered framework to interpret the electrocatalytic nitrogen cycle as an integrated redox network. Five key nitrogen conversion reactions are systematically analyzed, and five fundamental dimensions of electronic regulation are identified, including d‐band characteristics, oxidation and spin states, crystal field effects, defect‐induced electronic redistribution, and heterostructure‐enabled charge transfer. By correlating these electronic descriptors with reaction‐specific bottlenecks, this review unifies mechanistic understanding across reductive and oxidative pathways and highlights performance metrics central to sustainable engineering. This perspective positions electronic configuration as a system‐level design principle for advancing scalable, low‐carbon nitrogen utilization technologies.
🔗 Provenance — このレコードを発見したソース
- openalex https://doi.org/10.1002/cey2.70287first seen 2026-06-29 05:17:34 · last seen 2026-06-29 05:17:39
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