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蒸気圧縮冷凍システム向け環境調和型冷媒の進展

Advances in Eco-Friendly Refrigerants for Vapour Compression Refrigeration Systems (原題)

Christian Walsh Benjamin

Zenodoプレプリント2026-09-10#省エネ経営インパクト: コスト削減対象セクター: cross_sector
DOI: 10.5281/zenodo.22690138
原典: https://zenodo.org/records/22690138
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🤖 gxceed AI 要約

日本語

本論文は、CFC・HCFC・HFCからHFO・炭化水素・アンモニア・CO2といった低GWP冷媒への転換に関するレビューである。モントリオール議定書キガリ修正の規制動向を踏まえ、各冷媒の熱力学的特性・安全性・環境影響とVCRシステムのCOP・エネルギー効率を比較する。自然冷媒やHFO混合冷媒はGWPを大幅に削減しつつ競争力のある性能を示すが、可燃性・毒性・システム再設計が普及の障壁となる。

English

This review examines the shift from CFCs, HCFCs, and HFCs to low-GWP refrigerants such as HFOs, hydrocarbons, ammonia, and CO2 in vapour compression refrigeration. It compares thermodynamic, safety, and environmental properties alongside COP and energy efficiency, driven by the Kigali Amendment's phase-down. Natural refrigerants and HFO blends cut GWP substantially with competitive performance, though flammability, toxicity, and redesign needs remain barriers.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本はフロン排出抑制法やHFC規制により冷媒転換が進む。本レビューは低GWP冷媒の性能・安全課題を整理し、冷凍空調分野の脱炭素戦略や省エネ投資判断に資する。

In the global GX context

The Kigali Amendment and EU F-gas rules are reshaping global refrigerant markets. This review synthesizes low-GWP alternatives and their trade-offs, informing corporate decarbonization strategies in refrigeration and cooling under tightening disclosure and phase-down regimes.

👥 読者別の含意

🔬研究者:低GWP冷媒の熱力学的・安全特性とシステム性能の比較知見を提供する。

🏢実務担当者:冷凍空調設備の冷媒転換における性能・安全・再設計コストの判断材料となる。

🏛政策担当者:HFCフェーズダウン政策と低GWP冷媒普及の技術的障壁を理解するのに有用。

📄 Abstract(原文)

The refrigeration and air-conditioning sector play a central role in food preservation, thermal comfort, healthcare, and industrial processing, but the working fluids historically used in vapour compression refrigeration (VCR) systems — chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs) — contribute significantly to ozone depletion and global warming. International agreements such as the Montreal Protocol and its Kigali Amendment have accelerated the phase-down of high Global Warming Potential (GWP) refrigerants, driving research toward low-GWP alternatives including hydrofluoroolefins (HFOs), hydrocarbons (HC), ammonia (R717), and carbon dioxide (R744). This paper reviews the thermodynamic, safety, and environmental characteristics of conventional and eco-friendly refrigerants, compares their coefficient of performance (COP) and energy efficiency in VCR systems, and discusses the technical, safety, and regulatory challenges associated with their adoption. The review finds that natural refrigerants and HFO blends offer substantial reductions in GWP with competitive or improved energy performance, though flammability, toxicity, and system-redesign requirements remain key barriers to widespread implementation. The paper concludes with recommendations for future research directions, including refrigerant blend optimisation, safety engineering for mildly flammable fluids, and integration of renewable energy with next-generation refrigeration systems.

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