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Absorption and regeneration performance of AMP–PZ–DETA tri-solvent blend for post-combustion carbon dioxide (CO2) capture

AMP–PZ–DETA三元混合溶媒の燃焼後二酸化炭素(CO2)回収における吸収・再生性能評価 (AI 翻訳)

Chikezie Nwaoha, Xiujie Zhang, Bin Liu, Paitoon Tontiwachwuthikul

Chemical Engineering Journal Green and Sustainable📚 査読済 / ジャーナル2026-07-01#CCUSOrigin: CN経営インパクト: コスト削減対象セクター: power
DOI: 10.1016/j.cejgas.2026.100104
原典: https://doi.org/10.1016/j.cejgas.2026.100104

🤖 gxceed AI 要約

日本語

本研究では、AMP、PZ、DETAからなる三元混合アミン溶媒のCO2吸収・再生性能を実験的に評価した。結果、従来のMEAと比較して、平衡CO2負荷量33~61%向上、再生エネルギー53~58%削減を達成。さらに、AMP-DETA二元系よりも再生エネルギーが26~30%低く、組成調整による柔軟な運転が可能であることを示した。

English

This study experimentally evaluates a tri-solvent amine blend (AMP-PZ-DETA) for post-combustion CO2 capture. Compared to benchmark MEA, it achieves 33-61% higher equilibrium CO2 loading and 54-58% lower regeneration energy. The system also shows 26-30% lower energy than AMP-DETA blend, with operational flexibility through composition adjustment.

Unofficial AI-generated summary based on the public title and abstract. Not an official translation.

📝 gxceed 編集解説 — Why this matters

日本のGX文脈において

日本ではCCUSがGX実現の鍵技術の一つと位置づけられており、特に電力・産業分野でのCO2回収コスト低減が課題。本研究成果は、アミン系溶媒のエネルギー効率改善に寄与し、国内CCSプロジェクトやゼロエミッション火力発電への応用が期待される。

In the global GX context

CCUS is critical for global net-zero targets, and amine-based post-combustion capture remains the most mature technology. This paper demonstrates a promising solvent blend that significantly reduces regeneration energy, addressing the key cost barrier in carbon capture deployment worldwide.

👥 読者別の含意

🔬研究者:Provides experimental data on a novel tri-solvent blend, enabling comparison with other amine systems and optimization for lower energy penalty in CO2 capture.

🏢実務担当者:Offers insights for selecting solvent blends in commercial carbon capture projects, potentially reducing operational costs through lower regeneration energy.

🏛政策担当者:Highlights progress in CCUS technology that can inform R&D funding priorities and deployment incentives for carbon capture infrastructure.

📄 Abstract(原文)

This study evaluates the equilibrium CO 2 loading, CO 2 absorption capacity, cyclic capacity, initial CO₂ desorption rate, heat of absorption, heat of vaporization, and overall regeneration energy of a tri-solvent amine blend system comprising 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), and diethylenetriamine (DETA). The AMP concentration was fixed at 2 mol/L, while PZ and DETA concentrations each were varied between 0.5 and 1.5 mol/L, maintaining a total amine concentration of 4 mol/L (37–40 wt%). Experimental results demonstrate that the AMP–PZ–DETA tri-solvent blend system exhibits significantly higher equilibrium CO 2 loading (33.3–60.8%), CO 2 absorption capacity (3.8–26.9%), cyclic capacity (18.5–66.2%), initial CO₂ desorption rates (117–137%), while reducing regeneration energy by 53.8–57.8% relative to the benchmark monoethanolamine (MEA) solution, and lower regeneration energy (26.2–30.1%,) than the AMP–DETA bi-solvent blend. Furthermore, both the heat of absorption and heat of vaporization for the tri-solvent system were found to be lower than those of the AMP–DETA blend and MEA. The AMP–PZ–DETA tri-solvent blends also exhibited relative regeneration energy comparable to, and in several cases lower than, that of the optimal concentrations reported for recently investigated tri-solvent amine blend systems. Overall, the results indicate that the AMP–PZ–DETA system offers improved CO 2 absorption and regeneration characteristics, while the variation in tri-solvent blend composition highlights its operational flexibility in maintaining low energy requirements without compromising the CO 2 absorption and cyclic capacities for post-combustion CO₂ capture applications.

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