Metal-organic frameworks and their derivatives for CO2 electrocatalysis: From methods and designs to products.
CO2電解触媒のための金属有機構造体とその誘導体：方法と設計から生成物まで (AI 翻訳)
Sanusi Sule, Meng-Tao Zhou, Mulin Yu, Yu Tang, Sani Muhammad, I. T. Siraj, Xian‐Zhu Fu, Subiao Liu, Jingpeng Luo
🤖 gxceed AI 要約
日本語
本レビューは、CO2電解還元反応（eCO2RR）における金属有機構造体（MOF）とその誘導体の設計戦略と生成物選択性の関係を体系的に解説。金属ノードや有機リンカー、濡れ性などの役割に焦点を当て、設計-合成-生成物-メカニズムの枠組みで整理。将来の高性能材料開発に向けた課題と展望を示す。
English
This review systematically examines the interplay between design strategies and product selectivity in MOFs and MOF derivatives for electrochemical CO2 reduction. It emphasizes often-overlooked aspects such as metal nodes, organic linkers, and wettability, using a design-synthesis-product-mechanism framework. Perspectives on current limitations and future directions are provided.
Unofficial AI-generated summary based on the public title and abstract. Not an official translation.
📝 gxceed 編集解説 — Why this matters
日本のGX文脈において
日本ではCO2削減技術としてCCUSが注目されており、本レビューはMOFを用いた電解還元の設計指針を提供する。ただし直接的な政策連動は薄く、基礎研究としての位置づけ。
In the global GX context
This review contributes to the global CCUS literature by offering a structured framework for designing MOF-based electrocatalysts, which is relevant for carbon conversion technologies. It does not directly address disclosure or policy frameworks.
👥 読者別の含意
🔬研究者:Provides a comprehensive framework linking design strategies to product selectivity in MOF-based eCO2RR, useful for materials scientists.
📄 Abstract（原文）
Curtailing atmospheric CO2 from industrial processes and automobiles remains a pressing issue to be addressed in alleviating the existential threats of climate change. To this end, the electrochemical CO2 reduction reaction (eCO2RR) route, which utilizes metal-based catalysts to convert CO2 into valuable products, has emerged as a viable alternative to traditional carbon capture and conversion technologies. Metal-organic frameworks (MOFs) and their derivatives among metal-based materials stand out due to their large surface areas, tunable pore structures, and ability to accommodate various metal nodes and organic linkers. Despite extensive studies, a deep understanding of how MOF design strategies influence interfacial properties, reaction mechanisms, and ultimately product selectivity remains challenging. This review thus provides a unique perspective on eCO2RR using MOFs and MOF derivatives by examining the interplay between synthetic methods, design strategies, and product selectivity, with an emphasis on often-overlooked aspects, such as the specific roles of metal nodes, organic linkers, and wettability. Moreover, our work provides an eCO2RR-exclusive understanding by systematically examining how particular design strategies (e.g., morphology control, defect engineering, hybrid modulation, local microenvironment regulation, and interfacial properties optimization) are exploited to tune the interfacial properties of MOFs and MOF derivatives and their impacts on the selectivity toward specific product(s) through a "design-synthesis-product-mechanism" framework. Finally, our perspectives on the development of MOFs and MOF derivatives, including current limitations and ideas for future directions in designing high-performance materials for efficient eCO2RR to value-added products, are provided concisely.
🔗 Provenance — このレコードを発見したソース
- semanticscholar https://doi.org/10.1016/j.cis.2026.103839first seen 2026-05-06 00:04:17
gxceed は公開メタデータに基づく研究支援データセットです。要約・翻訳・解説は AI 支援で生成されています。 最終的な解釈・検証は利用者が原典資料に基づいて行うことを前提とします。